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TitleDistribution and Occurence of Polycyclic Aromatic Hydrocarbons (PAHs) in Sediments from the Mar Grande and Gulf of Taranto (Ionian Sea, Southern Italy).
AbstractMarine sediments from the Mar Grande and Gulf of Taranto were analysed for 17 parent PAHs, with molecular weight from 128 to 278 Daltons. The analyses were performed by gas chromatography coupled to mass spectrometry (GCMS). Total PAHs content in sediments ranged from 464 to 12522 g kg-1 dry wt for Mar Grande and from 593 to 72275 g kg-1 dry wt for Gulf of Taranto. The analytical results were compared with the published results for other coastal areas in the Mediterranean Sea. PAHs levels in the Gulf of Taranto sediments were the highest in the Mediterranean sea, while PAHs concentrations in Mar Grande were higher than the ones reported in the Adriatic and Cretan Sea and with the same order of magnitude of the ones known for coastal areas of the Western and the Eastern Mediterranean Sea. PAHs concentration ratios were consistent with the main source of these compounds, in most areas, being pyrolysis. Based on the comparison of both the individual and the total PAHs concentrations with proposed sediment quality guidelines, the acute biological effects on the marine organisms were probable, especially for the Gulf of Taranto, in which almost all PAHs concentrations in sediments were higher than the guidelines limit values. The statistical analysis effected by HCA and PCA methods was used in order to classify sediment samples and to identify accumulation areas.
SourceAnnali di chimica (Testo stamp.) 96 (1-2), pp. 51–64
KeywordsPOLYCYCLIC AROMATIC HYDROCARBONS (PAHS)SEDIMENTSGULF OF TARANTO
JournalAnnali di chimica (Testo stamp.)
EditorSocieta chimica italiana, Roma, Italia
Year2006
TypeArticolo in rivista
DOI10.1002/adic.200690006
AuthorsCardellicchio N., Buccolieri A., Giandomenico S., Lerario V.L. Lopez L., Pizzulli F.
Text6384 2006 10.1002/adic.200690006 ISI Web of Science WOS 000237015400004 POLYCYCLIC AROMATIC HYDROCARBONS PAHS SEDIMENTS GULF OF TARANTO Distribution and Occurence of Polycyclic Aromatic Hydrocarbons PAHs in Sediments from the Mar Grande and Gulf of Taranto Ionian Sea, Southern Italy . Cardellicchio N., Buccolieri A., Giandomenico S., Lerario V.L. Lopez L., Pizzulli F. CNR Institute for Coastal Marine Environment, via Roma 3, 74100 Taranto, Italy Department of Material Science, University of Lecce, via per Arnesano, 73100 Lecce, Italy Department of Chemistry, University of Bari, via Orabona 4, 70126 Bari, Italy Marine sediments from the Mar Grande and Gulf of Taranto were analysed for 17 parent PAHs, with molecular weight from 128 to 278 Daltons. The analyses were performed by gas chromatography coupled to mass spectrometry GCMS . Total PAHs content in sediments ranged from 464 to 12522 g kg 1 dry wt for Mar Grande and from 593 to 72275 g kg 1 dry wt for Gulf of Taranto. The analytical results were compared with the published results for other coastal areas in the Mediterranean Sea. PAHs levels in the Gulf of Taranto sediments were the highest in the Mediterranean sea, while PAHs concentrations in Mar Grande were higher than the ones reported in the Adriatic and Cretan Sea and with the same order of magnitude of the ones known for coastal areas of the Western and the Eastern Mediterranean Sea. PAHs concentration ratios were consistent with the main source of these compounds, in most areas, being pyrolysis. Based on the comparison of both the individual and the total PAHs concentrations with proposed sediment quality guidelines, the acute biological effects on the marine organisms were probable, especially for the Gulf of Taranto, in which almost all PAHs concentrations in sediments were higher than the guidelines limit values. The statistical analysis effected by HCA and PCA methods was used in order to classify sediment samples and to identify accumulation areas. 96 Annali2006 d Articolo pubblicato Annali_2006_d 0.pdf Articolo in rivista Societa chimica italiana 0003 4592 Annali di chimica Testo stamp. Annali di chimica Testo stamp. Ann. chim. Testo stamp. Annali di chimica. Testo stamp. santina.giandomenico GIANDOMENICO SANTINA nicola.cardellicchio CARDELLICCHIO NICOLA TA.P04.002.001 Fascia Costiera e Ambienti di Transizione analisi strutturale e funzionale delle componenti biotiche ed abiotiche degli ecosistemi per lo sviluppo sostenibile delle attivita