Title | Methodological approach for metal pollution evaluation in sediments collected from the Taranto Gulf (Ionian Sea, Southern Italy). |
Abstract | The concentrations of Hg, Cd, Pb, Cu, Ni, V, and Sn were determined in marine
sediments collected from Taranto Gulf (Ionian Sea, Southern Italy). The aim of
this article is to study the methodological approach in order to evaluate total
metal levels determined in marine sediments of a contaminated area (Taranto
Gulf, Southern Italy), to identify contaminated areas and to predict adverse
biological effects based on Sediment Quality Guidelines (SQGs). The results are
discussed in relation to geological characteristics of sediments in order to define
background levels and anthropogenic input. Experimental results were elaborated
by multivariate statistical techniques and Geographical Information System
(GIS) software. The geoaccumulation index Igeo and two sets of SQGs (in
particular (a) the threshold effect level (TEL), the probable effect level (PEL) and
(b) the effect range-low (ERL) and the effect range median (ERM)) have been
used for environmental evaluation of metal concentrations. Results show that in
Taranto coastal area, Mar Piccolo basin represents the most contaminated area.
A comparison with results from other Mediterranean areas demonstrates that for
some metals (such as Cd, Pb, and Hg) Taranto seas represent one of the most
polluted areas in the Mediterranean Sea. A comparison of metal levels with SQGs
also suggests an ecotoxicological risk for benthic organisms mainly in the first
inlet of Mar Piccolo. |
Source | Toxicological and environmental chemistry (Online) 91 (7), pp. 1273–1290 |
Keywords | marine sedimentsheavy metalsgeoaccumulation indexsediment |
Journal | Toxicological and environmental chemistry (Online) |
Editor | Gordon and Breach Publishing Group., Amsterdam, Paesi Bassi |
Year | 2009 |
Type | Articolo in rivista |
DOI | 10.1080/02772240802616494 |
Authors | N. Cardellicchio a*, A. Buccolieri b, A. Di Leo a, V. Librando c, Z. Minniti c and L. Spada a |
Text | 60052 2009 10.1080/02772240802616494 Scopus 2 s2.0 70350769084 marine sediments heavy metals geoaccumulation index sediment Methodological approach for metal pollution evaluation in sediments collected from the Taranto Gulf Ionian Sea, Southern Italy . N. Cardellicchio a , A. Buccolieri b, A. Di Leo a, V. Librando c, Z. Minniti c and L. Spada a N. Cardellicchio a , A. Buccolieri b, A. Di Leo a, V. Librando c, Z. Minniti c and L. Spada a a C.N.R., Institute for Coastal Marine Environment, via Roma 3, I 74100, Taranto, Italy; b University of Lecce, Department of Materials Science, via per Monteroni, I 73100, Lecce, Italy; c Research Centre for Analysis, Monitoring and Minimization Methods of Environmental Risk and Department of Chemistry, University of Catania, Viale Doria 6, I 95127, Catania, Italy The concentrations of Hg, Cd, Pb, Cu, Ni, V, and Sn were determined in marine sediments collected from Taranto Gulf Ionian Sea, Southern Italy . The aim of this article is to study the methodological approach in order to evaluate total metal levels determined in marine sediments of a contaminated area Taranto Gulf, Southern Italy , to identify contaminated areas and to predict adverse biological effects based on Sediment Quality Guidelines SQGs . The results are discussed in relation to geological characteristics of sediments in order to define background levels and anthropogenic input. Experimental results were elaborated by multivariate statistical techniques and Geographical Information System GIS software. The geoaccumulation index Igeo and two sets of SQGs in particular a the threshold effect level TEL , the probable effect level PEL and b the effect range low ERL and the effect range median ERM have been used for environmental evaluation of metal concentrations. Results show that in Taranto coastal area, Mar Piccolo basin represents the most contaminated area. A comparison with results from other Mediterranean areas demonstrates that for some metals such as Cd, Pb, and Hg Taranto seas represent one of the most polluted areas in the Mediterranean Sea. A comparison of metal levels with SQGs also suggests an ecotoxicological risk for benthic organisms mainly in the first inlet of Mar Piccolo. 91 articolo pubblicato Toxic_EnvironChem_2009.pdf Articolo in rivista Gordon and Breach Publishing Group. 1029 0486 Toxicological and environmental chemistry Online Toxicological and environmental chemistry Online Toxicol. environ. chem. Online antonella.dileo DI LEO ANTONELLA lucia.spada SPADA LUCIA nicola.cardellicchio CARDELLICCHIO NICOLA TA.P05.016.001 Impatti Antropici sulla fascia costiera metodologie di monitoraggio e remediation di siti e sedimenti contaminati |