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DatoValore
TitleDetermination of perfluoroalkyl acids in different tissues of graminaceous plants
AbstractA method for the determination of 12 perfluoroalkyl acids (PFAA) in vegetal samples was proposed. The analytical procedure was developed to optimize the detection of short-chain PFAA (C < 8) due to their higher potential to be translocated and bioaccumulated in plants than long-chain congeners. The method, based on ultrasonic extraction, clean-up and HPLC-MS/MS analysis, determined PFAA in different plant tissues allowing the PFAA distribution and partition in vegetal compartments to be studied. The performance of this analytical procedure was validated by analysing samples (root, stem and leaf) of reed grass. The validated method was then applied to graminaceous plants from an agricultural area impacted by a fluorochemical plant discharge (Northern Italy). The PFAA congeners were detected in most of the samples with sigma PFAA concentrations in the whole plant ranging from
SourceAnalytical methods (Print)
Keywordspfasplant uptakeanalytical method
JournalAnalytical methods (Print)
EditorRSC Publishing,, Cambridge, Regno Unito
Year2021
TypeArticolo in rivista
DOI10.1039/d0ay02226h
AuthorsFerrario, Claudia; Valsecchi, Sara; Lava, Roberto; Bonato, Marco; Polesello, Stefano
Text450156 2021 10.1039/d0ay02226h ISI Web of Science WOS 000631581000001 pfas plant uptake analytical method Determination of perfluoroalkyl acids in different tissues of graminaceous plants Ferrario, Claudia; Valsecchi, Sara; Lava, Roberto; Bonato, Marco; Polesello, Stefano Natl Res Council Italy IRSA CNR; ARPAV Reg Environm Agcy Veneto; Univ Padua A method for the determination of 12 perfluoroalkyl acids PFAA in vegetal samples was proposed. The analytical procedure was developed to optimize the detection of short chain PFAA C < 8 due to their higher potential to be translocated and bioaccumulated in plants than long chain congeners. The method, based on ultrasonic extraction, clean up and HPLC MS/MS analysis, determined PFAA in different plant tissues allowing the PFAA distribution and partition in vegetal compartments to be studied. The performance of this analytical procedure was validated by analysing samples root, stem and leaf of reed grass. The validated method was then applied to graminaceous plants from an agricultural area impacted by a fluorochemical plant discharge Northern Italy . The PFAA congeners were detected in most of the samples with sigma PFAA concentrations in the whole plant ranging from