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TitleTowards a continuous two-phase partitioning bioreactor for xenobiotic removal
AbstractThe removal of a xenobiotic (4-chlorophenol) from contaminated water was investigated in a simulated continuous two-phase partitioning bioreactor (C-TPPB), fitted with coiled tubing comprised of a specifically-selected extruded polymer, Hytrel 8206. Wastewater flowed inside the tubing, the pollutant diffused through the tubing wall, and was removed in the aqueous bioreactor phase at typical biological removal rates in the C-TTPB simulated by varying aqueous phase throughput to the reactor. Operating over a range of influent substrate concentrations (500-1500 mg L-1) and hydraulic retention times in the tubing (4-8 h), overall mass transfer coefficients were 1.7-3.5 × 10-7 m s-1, with the highest value corresponding to the highest tubing flow rate. Corresponding mass transfer rates are of the same order as biological removal rates, and thus do notlimitthe removal process. The C-TPPB showed good performance over all organic and hydraulic loading ranges, with removal efficiencies of 4CP in the tubing wastewater stream always >=96%. Additionally, the presence of the Hytrel tubing was able to buffer increases in organic loading to the hybrid system, enhancing overall process stability. Biological testing of the C-TPPB confirmed the abiotic test results demonstrating even higher 4-chlorophenol removal efficiency (~99%) in the tubing stream.
SourceJournal of hazardous materials (Print) 317, pp. 403–415
KeywordsContinuous two-phase partitioning bioreactorMass transferPolymer tubingWastewater treatmentXenobiotics
JournalJournal of hazardous materials (Print)
EditorElsevier, New York ;, Paesi Bassi
Year2016
TypeArticolo in rivista
DOI10.1016/j.jhazmat.2016.05.092
AuthorsTomei M.; Mosca Angelucci D.; Daugulis A.J.
Text358072 2016 10.1016/j.jhazmat.2016.05.092 Scopus 2 s2.0 84974814374 ISI Web of Science WOS WOS 000381533400044 Continuous two phase partitioning bioreactor Mass transfer Polymer tubing Wastewater treatment Xenobiotics Towards a continuous two phase partitioning bioreactor for xenobiotic removal Tomei M.; Mosca Angelucci D.; Daugulis A.J. Water Research Institute, C.N.R., Via Salaria km 29.300, CP 10, Monterotondo Stazione, Rome, 00015, Italy; Department of Chemical Engineering, Queen s University, Kingston, ON, K7 L 3N6, Canada The removal of a xenobiotic 4 chlorophenol from contaminated water was investigated in a simulated continuous two phase partitioning bioreactor C TPPB , fitted with coiled tubing comprised of a specifically selected extruded polymer, Hytrel 8206. Wastewater flowed inside the tubing, the pollutant diffused through the tubing wall, and was removed in the aqueous bioreactor phase at typical biological removal rates in the C TTPB simulated by varying aqueous phase throughput to the reactor. Operating over a range of influent substrate concentrations 500 1500 mg L 1 and hydraulic retention times in the tubing 4 8 h , overall mass transfer coefficients were 1.7 3.5 × 10 7 m s 1, with the highest value corresponding to the highest tubing flow rate. Corresponding mass transfer rates are of the same order as biological removal rates, and thus do notlimitthe removal process. The C TPPB showed good performance over all organic and hydraulic loading ranges, with removal efficiencies of 4CP in the tubing wastewater stream always >=96%. Additionally, the presence of the Hytrel tubing was able to buffer increases in organic loading to the hybrid system, enhancing overall process stability. Biological testing of the C TPPB confirmed the abiotic test results demonstrating even higher 4 chlorophenol removal efficiency 99% in the tubing stream. 317 Published version http //www.scopus.com/inward/record.url eid=2 s2.0 84974814374 partnerID=q2rCbXpz Towards a continuous two phase partitioning bioreactor for xenobiotic removal Tipo documento pdf file Permessi per l accesso al file Riservato su sistemi CNR previa autenticazione JHM_2016.pdf Articolo in rivista Elsevier 0304 3894 Journal of hazardous materials Print Journal of hazardous materials Print J. hazard. mater. Print Journal of hazardous materials. Print domenica.moscaangelucci MOSCA ANGELUCCI DOMENICA mariaconcetta.tomei TOMEI MARIA CONCETTA TA.P07.002.005 Rimozione di composti xenobiotici da acque di scarico