Scheda di dettaglio – i prodotti della ricerca
| Dato | Valore |
|---|---|
| Title | Molecular recognition of the fungicide carbendazim by a molecular imprinted polymer obtained through a mimic template approach |
| Abstract | A molecularly imprinted polymer recognizing the fungicide carbendazim was prepared using a mimicking template approach. Methyl-3-propylcarbamoyl-1H-benzimidazol-2-ylcarbamate was synthesized and used as a mimic template for polymer preparation. Selectivity of this polymer for carbendazim and structurally related substances (the template, fluberidazole, rabenzazole, thiabendazole, and benomyl and its two degradation products) was evaluated by liquid chromatography. Results demonstrate that imprinted polymer shows significant recognition properties for carbendazim, whereas the mimic and other carbendazim-related molecules are not recognized. This peculiar selectivity pattern can be explained as an imprinting effect due to the in situ formation of carbendazim from mimic degradation during the polymerization process. Copyright © Taylor & Francis Group, LLC. |
| Source | Analytical letters 42 (5), pp. 807–820 |
| Keywords | CarbendazimFungicideMimic templateMolecular imprintingMolecular recognitionSelectivity |
| Journal | Analytical letters |
| Editor | M. Dekker,, New York, N.Y., Stati Uniti d'America |
| Year | 2009 |
| Type | Articolo in rivista |
| DOI | 10.1080/00032710802677183 |
| Authors | Anfossi, Laura; Baggiani, Claudio; Baravalle, Patrizia; Giovannoli, Cristina; Guzzella, Licia; Pozzoni, Fiorenzo |
| Text | 309154 2009 10.1080/00032710802677183 Scopus 2 s2.0 68249156453 Carbendazim Fungicide Mimic template Molecular imprinting Molecular recognition Selectivity Molecular recognition of the fungicide carbendazim by a molecular imprinted polymer obtained through a mimic template approach Anfossi, Laura; Baggiani, Claudio; Baravalle, Patrizia; Giovannoli, Cristina; Guzzella, Licia; Pozzoni, Fiorenzo Universita degli Studi di Torino; Consiglio Nazionale delle Ricerche A molecularly imprinted polymer recognizing the fungicide carbendazim was prepared using a mimicking template approach. Methyl 3 propylcarbamoyl 1H benzimidazol 2 ylcarbamate was synthesized and used as a mimic template for polymer preparation. Selectivity of this polymer for carbendazim and structurally related substances the template, fluberidazole, rabenzazole, thiabendazole, and benomyl and its two degradation products was evaluated by liquid chromatography. Results demonstrate that imprinted polymer shows significant recognition properties for carbendazim, whereas the mimic and other carbendazim related molecules are not recognized. This peculiar selectivity pattern can be explained as an imprinting effect due to the in situ formation of carbendazim from mimic degradation during the polymerization process. Copyright © Taylor Francis Group, LLC. 42 http //www.scopus.com/record/display.url eid=2 s2.0 68249156453 origin=inward Articolo in rivista M. Dekker, 0003 2719 Analytical letters Analytical letters Anal Lett Analytical letters International journal for rapid communication Chemical analysis Clinical and biochemical analysis liciamaria.guzzella GUZZELLA LICIA MARIA TA.P04.021.007 Diffusione, ripartizione, bioaccumulo e trasformazione di inquinanti in ecosistemi acquatici |