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DatoValore
TitleComparison of UV/H2O2 based AOP as an end treatment or integrated with biological degradation for treating landfill leachates
AbstractThe application of a biological treatment together with a chemical oxidation process was investigated. In particular, the effectiveness of the biological treatment followed by a UV/H2O2-based advanced oxidation process (AOP) used as an end treatment was compared with that in which the same AOP was integrated with biological degradation for treating a medium age sanitary landfill leachate. The results show that better performance with removal efficiencies higher than 80% for all investigating parameters was obtained when AOP was integrated with the biological treatment, thus allowing the discharge limits to be met. This was due to the biological removal of the biodegradable compounds produced by UV/H2O2 treatment. Instead, UV/H2O2-based AOP biodegradability enhancement gave no advantage when it was used as an end treatment. Finally, the results show that H2O2 alone (i.e., without UV power) was quite ineffective either as a mineralizing or as a biodegradability enhancing agent and that the only reactive species was essentially the hydroxyl free radical OH.
SourceChemical engineering journal ( Print) 218, pp. 133–137
KeywordsLandfill leachate treatmentUV/H2O2-based AOPHydrogen peroxide treatmentBiological treatment
JournalChemical engineering journal ( Print)
EditorElsevier Sequoia, Lausanne, Svizzera
Year2013
TypeArticolo in rivista
DOI10.1016/j.cej.2012.12.086
AuthorsDel Moro G., Mancini A., Mascolo G., Di Iaconi C.
Text241755 2013 10.1016/j.cej.2012.12.086 ISI Web of Science WOS 000317255700017 Landfill leachate treatment UV/H2O2 based AOP Hydrogen peroxide treatment Biological treatment Comparison of UV/H2O2 based AOP as an end treatment or integrated with biological degradation for treating landfill leachates Del Moro G., Mancini A., Mascolo G., Di Iaconi C. Water Research Institute CNR, Via F. De Blasio 5, 70123 Bari, Italy The application of a biological treatment together with a chemical oxidation process was investigated. In particular, the effectiveness of the biological treatment followed by a UV/H2O2 based advanced oxidation process AOP used as an end treatment was compared with that in which the same AOP was integrated with biological degradation for treating a medium age sanitary landfill leachate. The results show that better performance with removal efficiencies higher than 80% for all investigating parameters was obtained when AOP was integrated with the biological treatment, thus allowing the discharge limits to be met. This was due to the biological removal of the biodegradable compounds produced by UV/H2O2 treatment. Instead, UV/H2O2 based AOP biodegradability enhancement gave no advantage when it was used as an end treatment. Finally, the results show that H2O2 alone i.e., without UV power was quite ineffective either as a mineralizing or as a biodegradability enhancing agent and that the only reactive species was essentially the hydroxyl free radical OH. 218 Published version http //www.sciencedirect.com/science/article/pii/S1385894713000247 Articolo in rivista Elsevier Sequoia 1385 8947 Chemical engineering journal Print Chemical engineering journal Print Chem. eng. j. Print Chemical engineering journal. Print guido.delmoro DEL MORO GUIDO MANCINI ANNALISA claudio.diiaconi DI IACONI CLAUDIO giuseppe.mascolo MASCOLO GIUSEPPE TA.P07.002.003 Integrazione di processi chimici e biologici