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DatoValore
TitleReactivity of two models of non-ionic surfactants with ozone
AbstractAbstract--The ozonation of ethylene glycol and diethylene glycol mono-n-octylether (models of non-ionic surfactants) has been performed in aqueous solution at pH 4 and pH 9.5. The experiments at acidic pH show that the methylene groups adjacent to the ethereal oxygens are transformed into carbonyl groups. At alkaline pH the aliphatic chain is cleaved. Kinetic experiments allow to suggest a reaction mechanism
SourceWater research (Oxf.) 31, pp. 1839–1846
Keywordsaqueous ozonationnon-ionic surfactants
JournalWater research (Oxf.)
EditorPergamon Press., New York, Regno Unito
Year1997
TypeArticolo in rivista
AuthorsBrambilla A., Bolzacchini E., Orlandi M., Polesello S., Rindone B.
Text233511 1997 aqueous ozonation non ionic surfactants Reactivity of two models of non ionic surfactants with ozone Brambilla A., Bolzacchini E., Orlandi M., Polesello S., Rindone B. Universita degli studi di Milano Abstract The ozonation of ethylene glycol and diethylene glycol mono n octylether models of non ionic surfactants has been performed in aqueous solution at pH 4 and pH 9.5. The experiments at acidic pH show that the methylene groups adjacent to the ethereal oxygens are transformed into carbonyl groups. At alkaline pH the aliphatic chain is cleaved. Kinetic experiments allow to suggest a reaction mechanism 31 articolo 97BrambillaWaterRes97Ozone.pdf Articolo in rivista Pergamon Press. 0043 1354 Water research Oxf. Water research Oxf. Water res. Oxf. Water research. Oxf. stefano.polesello POLESELLO STEFANO