Scheda di dettaglio – i prodotti della ricerca
Dato | Valore |
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Title | Ozone oxidation of polyethoxylated alcohols |
Abstract | The ozonation of a polyethoxylated alcohol (typical of one type of detergent) mixture was performed in aqueous solution under different conditions of pH, reaction time and hydrogen peroxide addition. Surfactant degradation was monitored by TOC measurements. The optimal degradation conditions were found to be at pH ffi 7.5 with hydrogen peroxide addition. Inspection of the reaction products was carried out by GC-MS and GC-FTIR analysis of the silylated mixtures. The main oxidation products of ethoxylated alcohols are dicarboxylic acids. |
Source | Water research (Oxf.) 27, pp. 1313–1322 |
Keywords | aqueous ozonationnon-ionic surfactantspolyethoxylated alcoholsGC-MS |
Journal | Water research (Oxf.) |
Editor | Pergamon Press., New York, Regno Unito |
Year | 1993 |
Type | Articolo in rivista |
Authors | Brambilla A., Calvosa L., Monteverdi A., Polesello S., Rindone B., |
Text | 233479 1993 aqueous ozonation non ionic surfactants polyethoxylated alcohols GC MS Ozone oxidation of polyethoxylated alcohols Brambilla A., Calvosa L., Monteverdi A., Polesello S., Rindone B., Universita degli Studi di Milano The ozonation of a polyethoxylated alcohol typical of one type of detergent mixture was performed in aqueous solution under different conditions of pH, reaction time and hydrogen peroxide addition. Surfactant degradation was monitored by TOC measurements. The optimal degradation conditions were found to be at pH ffi 7.5 with hydrogen peroxide addition. Inspection of the reaction products was carried out by GC MS and GC FTIR analysis of the silylated mixtures. The main oxidation products of ethoxylated alcohols are dicarboxylic acids. 27 articolo 93BrambillaWaterRes93Ozone.pdf Articolo in rivista Pergamon Press. 0043 1354 Water research Oxf. Water research Oxf. Water res. Oxf. Water research. Oxf. stefano.polesello POLESELLO STEFANO |